Mineralogists seek out benitoite because it's the simplest of the ring silicates, with its molecular ring being composed of only three silica tetrahedra. (Beryl, the most familiar ring silicate, has a ring of six.) And its crystals are in the rare ditrigonal-bipyramidal symmetry class, their molecular arrangement displaying a triangle shape that geometrically is actually a bizarre inside-out hexagon (this is not correct technical crystallographic language, you understand).
Benitoite was discovered in 1907 and was later named the state gemstone of California.


